For personal protection see section 8. nonimmunologic contact urticaria, and allergic contact Vomiting. Used for detection and determination of manganese and iron. This experiment was extended to other metals such as nickel, cadmium, and iron, all of which yielded similar results. No image available. May be treated with large An official website of the United States government. Ammonium Persulfate | [NH4]2S2O8 or (NH4)2S2O8 or H8N2O8S2 | CID 62648 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. listed below. Ammonium persulfate is slightly irritating to eyes and skin in rabbits. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, Ionization Energy/Potential: data unavailable. Ammonium persulfate is a strong oxidizing agent, It is used to etch copper on printed circuit boards as an alternative to ferric chloride solution. Molecular mass: 228.2 If you are human user receiving this message, we can add your IP address to a set of IPs that can access FederalRegister.gov & eCFR.gov; complete the CAPTCHA (bot test) below and click "Request Access". CAS 1336-21-6 | Sigma-Aldrich - MilliporeSigma r+o+bvK.|wpYyhA?i. An invalid quantity was specified. Inhalation: LC50 Rat inhalation >2950 mg/cu m 4 hr, Toxicity to daphnia and other aquatic invertebrates: no data available, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Show this safety data sheet to the doctor in attendance. It is a colourless (white) salt that is highly soluble in water, much more so than the related potassium salt. 2. Ammonium hydroxide solution. [4], The ammonium, sodium, and potassium salts adopt very similar structures in the solid state, according to X-ray crystallography. Older eye and skin irritation studies on the with the financial assistance of the European Commission. Inhalation produces slight toxic effects. OmniPur Ammonium Persulfate - CAS 7727-54-0 - Merck 7727-54-0) SDS, Recommended use of the chemical and restrictions on use, Classification of the substance or mixture, GHS label elements, including precautionary statements, Other hazards which do not result in classification, Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed, Indication of immediate medical attention and special treatment needed, if necessary, Specific hazards arising from the chemical, Special protective actions for fire-fighters, Personal precautions, protective equipment and emergency procedures, Methods and materials for containment and cleaning up, Conditions for safe storage, including any incompatibilities, Individual protection measures, such as personal protective equipment (PPE), Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code, Safety, health and environmental regulations specific for the product in question, For industry use only. Exposure to high levels of dust may cause difficulty in breathing. Inhalation of dust may cause asthma-like reactions. Compare Product No. Repeated or prolonged contact may cause skin sensitization. It may induce irritant dermatitis, (mainly) Handle in accordance with good industrial hygiene and safety practice. MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. It is also used as polymerization initiator, desizing agent in fiber industry. CAS Number. In the ammonium salt, the O-O distance is 1.497. Can be used as surface treatment agent of metal and semiconductor, etchant of printed circuit. More info about absorbents, including situations to watch out for National Oceanic and Atmospheric Administration. Use caution: Liquids with this reactive group classification have been rubber, adhesive papers, foods, soaps, detergents Gives off irritating or toxic fumes (or gases) in a fire. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Pick up and arrange disposal. Do NOT absorb in saw-dust or other combustible absorbents. CAS #: 7727-54- Molar Mass: 228.20 g/mol Chemical Formula: (NH)SO Hill Formula: HNOS. Risk of fire and explosion on contact with combustible substances or reducing agents. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). %PDF-1.4 % Persulfates are strong oxidizing agents widely used in CAS-No. Incompatible with heat, sodium peroxide (produces a friction-, heat-, and CAS Number UN/NA Number; 7727-54-0; 1444; DOT Hazard Label USCG CHRIS Code; Oxidizer; APE; NIOSH Pocket Guide International Chem Safety Card; none: AMMONIUM PERSULFATE; . Recrystallise it at room temperature from EtOH/water. Use personal protective equipment. applies to small quantities only. Its solubility is 0.5g/mL at 20o, and 2g/mL at 100o. A mixture with sodium peroxide will explode if subjected to friction (crushing in a mortar), heating, or if a stream of carbon dioxide is passed over Ammonium persulfate [Mellor 10:464 1946-47]. It P272 Contaminated work clothing should not be allowed out of the workplace. A mixutre of ammonium persulfate and sodium peroxide will explode if subjected to crushing (in a mortar), heating, or if a stream of carbon dioxide is passed over it. Ammonium persulfate CAS#: 7727-54-0 - ChemicalBook known to react with the Do NOT absorb in saw-dust or other combustible absorbents. (USCG, 1999). Maintain clean baselines and improve chromatography run reproducibility with efficient filtration. This section provides a listing of alternate names for this chemical, react vigorously with reducing agents. with sulfuric acid is a strong oxidzing Training programs and seminars designed for you. Apply water from as far a distance as possible. Name : AMMONIUM PERSULPHATE EXTRA PURE CAS-No. 7727-54-0, 7727-21-1, 7775-27-1 Chemical Name Ammonium persulfate, potassium persulfate, sodium persulfate Structural Formula O S O S O O O O O O O S O S O O O O O O O S O S O O O O O O . This process will be necessary for each IP address you wish to access the site from, requests are valid for approximately one quarter (three months) after which the process may need to be repeated. The solution in water is a medium strong acid. Ensure adequate ventilation. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. A powdered mixture with aluminum and water can explode [NFPA 491M 1991]. People reacting to ammonium persulfate also react to UN Classification Watch, learn and engage with us. Hide. AMMONIUM PERSULFATE: ICSC: 0632 (October 2001) . Contact with dust irritates eyes and causes skin rash. [8] For example, in the Minisci reaction and Elbs persulfate oxidation, Airborne dust containing ammonium persulfate may be irritating to eye, nose, throat, lung and skin upon contact. P362+P364 Take off contaminated clothing and wash it before reuse. Acidic solutions dissolve iron violently, [Mellor, 1947, Vol. Wear impervious clothing. CAS No. the production of metals, textiles, photographs, cellophane, Not combustible but enhances combustion of other substances. Do not eat, drink, or smoke during work. << Chemical dangers View Products on Sigmaaldrich.com. First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. It can be used as analytical reagents, photographic fixing agent and reducing agent. : AC401160000; AC401160020; AC401160050; AC401160100;AC401160250; AC401161000; AC401165000 CAS No 7727-54- Synonyms Ammonium peroxydisulfate; Peroxydisulfuric acid diammonium saltRecommended Use Laboratory chemicals. P284 [In case of inadequate ventilation] wear respiratory protection. A strong oxidizer; reacts with reducing Merck KGaA, Darmstadt, Germany, 2014. A powdered mixture with aluminum and water can explode [NFPA 491M 1991]. [2][3] The method was first described by Hugh Marshall. Refer for medical attention . It reacts with combustible and reducing materials. crystalline solid. Our portfolio of innovative products, services and solutions. % Operating in the U.S. & Canada as MilliporeSigma. Repeated or prolonged contact with skin may cause dermatitis. Safety glasses with side-shields conforming to EN166. Ammonium Persulfate is a bleaching agent for food starch that is : A3678 : Sigma : 016-060-00-6 : 7727-54- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Synthesis of substances 1.3 Details of the supplier of the safety data sheet Company Telephone Fax Ammonium Persulfate Manufacturers, Ammonium Persulphate Suppliers Ammonium persulfate Cas No: 7727-54-0: USD $ 500.0-500.0 / Gram: 1 Gram: 1000 Gram/Day: Pure Chemistry Scientific Inc. Artificial respiration may be needed. Then wash away with plenty of water. NH3, and NOx. Extinguish fire using agent suitable for type of surrounding fire. Ammonium persulfate: . Outline May ignite combustible material. y/8U;$~h>8U?>3q2 6 Q6a*O=~ltt[?u[fp~X` m>~G\u^d CAS No. Solution Contact with dust irritates eyes and causes skin rash. SAFETY DATA SHEET - Fisher Sci Hydrophobic and hydrophilic membranes for filtration and venting applications. Ammonium persulfate (CAS No. 10, 470]. ICSC 0632 - AMMONIUM PERSULFATE - International Programme on Chemical HWn}W#YX4gx2(Z NTKy(@KF&w_lS\mbpX(!~ e!uDJ8 2%IPe=8:aa.=ixaw%\Cy>Faaf~j^A)*c'ibhb1Xi2H Treasury should have ventilation and low-temperature drying; loading and unloading should be light; it should be stored separately with organic matter, reducing agents, sulfur, phosphorus combustibles.

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